Product ID:CITRIKLEEN HD
MSDS Date:01/05/1999
FSC:7930
NIIN:01-329-7434
Status Code:A
MSDS Number: CLMRF

PENETONE CORP / SUB OF WEST CHEMICAL PRODUCTS INC

74 HUDSON AVE
TENAFLY, NJ 07670
US

Emergency Phone: (800)424-9300

Info Phone: 201-567-3000

Preparer: HENRY SIMMONS

Cage: 56883

PENETONE CORP

TENAFLY, NJ 07670 US

Telephone: 201-567-3000

Cage: 56883

D-LIMONENE

CAS: 5989-27-5

RTECS: GW6360000

MONOETHANOLAMINE

CAS: 141-43-5

RTECS: KJ5775000

OSHA PEL 6 MG/M3;3 PPM

ACGIH TLV: 7.5 MG/M3;3 PPM

DIETHANOLAMINE

CAS: 111-42-2

RTECS: KL2975000

ACGIH TLV: 2 MG/M3;0.46 PPM

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

Health Hazards Acute and Chronic:CHRONIC: INFLAMMATION OF MUCOUS
MEMBRANES AND RESPIRATORY TRACT MAY OCCUR UPON BREATHING OF MIST.
INGESTION OF LARGE AMOUNTS OF D?LIMONENE HAS CAUSE LIVER DAMAGE IN
MALE RATS OF MICE IN BOTH SPECIES. INGESTION OF LARGE AMOUNTS OF
MONOETHANOLAMINE HAS CAUSED KIDNEY AND LIVER DAMAGE IN LABORATORY
ANIMALS. AN INCREASED EVIDENCE OF LIVER TUMORS IN BOTH SEXES OF
MICE AND AN INCREASED INCIDENCE OF KIDNE Y TUMORS IN MALE MICE
DERMALLY EXPOSED FOR THEIR LIFETIME TO DIETHANOLAMINE WAS OBSERVED.
THE SIGNIFICANCE OF THESE FINDINGS AND THESE FINDINGS AND THEIR
RELEVANCE TO HUMANS ARE NOT CLEAR AS DIETHANOL AMINE WAS NOT
GENOTOXIC.
Effects of Overexposure:EYE CONTACT: MAY CAUSE IRRITATION OR BURNS TO
EYES ON PROLONGED CONTACT. HIGH VAPOR CONCENTRATION MAY BE
IRRITATING. SKIN CONTACT: FREQUENT OR PROLONGED MAY IRRITATE OR
DRY THE SKIN, CAUSE DERMATITIS OR CAUSE BURNS. SKIN CONTACT MAY
AGGRAVATE AN EXISTING DERMATITIS CONDITION. INHALATION: HIGH
VAPOR/AEROSOL CONCENTRATIONS ARE IRRITATING OR MAY CAUSE BURNS TO
THE RESPIRATORY TRACT, MAY CAUSE HEADA CHES, DIZZINESS, ANESTHESIA,
DROWSINESS, AND OTHER CENTRAL NERVOUS SYSTEM EFFECTS. INGESTION:
SMALL AMOUNTS OF THIS LIQUID MAY BE DRAWN INTO THE LUNGS BE EITHER
SWALLOWING OR VOMITING. THIS MAY CAUSE SEVERE AND DELAYED HEATH
EFFECTS.

First Aid:EYE CONTACT: FLUSH EYES WITH LARGE AMOUNTS OF WATER. SEE
PHYSICIAN IMMEDIATELY. SKIN CONTACT: FLUSH SKIN WITH LARGE AMOUNTS
OF WATER. REMOVE CONTAMINATED CLOTHING AND LAUNDER REUSE. IF SKIN
IRRITATIO N DEVELOPS OR PERSIST, CONSULT PHYSICIAN. INHALATION:
REMOVE PERSON TO FRESH AIR. ADMINISTER OXYGEN OR ARTIFICIAL
RESPIRATION AS NEEDED. CALL A PHYSICIAN IMMEDIATELY. INGESTION: IF
SWALLOWED, GIVE P LENTY OF MILK OR WATER. DO NOT INDUCE VOMITING.
USE A STOMACH PUMP. CALL A PHYSICIAN IMMEDIATELY.

Flash Point Method:PMCC
Flash Point:=51.7C, 125.F
Fire Fighting Procedures:EITHER ALLOW FIRE TO BURN UNDER CONTROLLED OR
EXTINGUISH WITH WATER, FORM, OR DRY CHEMICAL. COOL, EXPOSED
CONTAINERS WITH SPRAY.
Unusual Fire/Explosion Hazard:SMOKES, FUMES, AND OXIDES OF CARBON AND
NITROGEN.

Spill Release Procedures:LAND SPILLS: ELIMINATE SOURCES OF IGNITION.
FOR SMALL SPILLS. USE ABSORBENT MATERIAL SUCH AS TOWELS OR
ABSORBENT POWDERS. PUT ALL MATERIAL INTO PROPER WASTE DISPOSAL WITH
LID TIGHTLY COVERED. SOLVENT SOAKED MATERIALS MAY SPONTANEOUSLY
COMBAT. FOR LARGER SPILLS, DIKE SPILL, RECOVER FREE LIQUID, AND USE
ABSORBENT MATERIAL TO DRY AREA. WATER SPILLS: REMOVE PRODUCT FROM
WATER SURFACES BY SKIMMING.

Handling and Storage Precautions:AMBIENT. DO NOT STORE ABOVE 120F.
GENERAL: KEEP AWAY FROM HEAT SOURCES, OPEN FLAMES, AND OTHER
IGNITION SOURCES. DO NOT STORE NEAR STRONG OXIDANTS.

Ventilation:NONE NEEDED UNDER NORMAL CONDITIONS. AN ORGANIC VAPOR MASK
SHOULD BE USED IF THE TLV IS EXCEEDED AND A PARTICLE MASK IF THE
PRODUCT IS SPRAYED.
Protective Gloves:SOLVENT RESISTANT GLOVES SHOULD BE USED.
Eye Protection:SAFETY GLASSES ARE RECOMMENDED FOR ALL WORKPLACE
CONDITIONS.
Other Protective Equipment:OTHER PROTECTIVE GEAR, INCLUDING SPLASH
PROOF GOGGLES OR FACE SHIELD, RUBBER BOOTS, APRON, GAUNTLETS, OR A
RAIN GEAR SHOULD BE WORN DEPENDING ON HOW THE PRODUCT IS USED.
Supplemental Safety and Health

Boiling Pt:=100.C, 212.F
Vapor Pres:EQUAL TO WATER
Vapor Density:= TO WATER
Spec Gravity:0..97
pH:11.2
Evaporation Rate & Reference:EQUAL TO WATER
Solubility in Water:EMULSFIES
Appearance and Odor:CLEAR AMBER LIQUID WITH CITRUS WINTERGREEN COLOR
Percent Volatiles by Volume:50

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:STRONG OXIDIZING AGENTS

SARA Title III Information:311/312 HAZARD CATEGORIES: ACUTE HEALTH,
CHRONIC HEALTH, FIRE 313 REPORTABLE INGREDIENTS: DIETHYLENE
GLYCOL MONOBUTYL ETHER CAS#112-34-5 <10% DIETHANOLAMINE
CAS#111-42-2 <2%
Federal Regulatory Information:CERLA THIS PRODUCT CONTAINS FOLLOWING
REPORTABLE MATERIAL. DIETHANOLAMINE CAS#111-42-2 RQ=1LB RCRA HAZARD
CLASS D001 IGNITABLE HAZARDOUS WASTE, D002 CORROSIVE HAZARDOUS
WASTE. SCAQMD INFORMATION IS T HERE A PHOTOCHEMICALLY MATERIAL
PRESENT? YES WHAT IS THE % BY VOLUME OF PHOTOCHEMICALLY REACTIVE
MATERIAL? ABOUT 30. WHAT IS THE VOC CONTENT? 520 G/L. WHAT IS THE
VAPOR PRESSURE OF VOC'S? 0.18 MM HG @ 20C.
State Regulatory Information:NEW JERSEY RIGHT TO KNOW ACT THIS PRODUCT
CONTAINS WATER (CAS#7732-18-5), D?LIMONENE (CAS#5989-27-5),
MONOETHANOLAMMONIUM FATTY ACID SOAP (CAS#68440-25-5), DIETHLENE
GLYCOL MONOBUTYL ETHER (CAS#112-3 4-5), MONOETHANLAMINE
(CAS#141-43-5), NONYLPHENOL ETHOXYLATE (CAS#9016-45-9) AND
DIETHANOLAMINE (CAS#111-42-2) CALIFORNIA PROPOSITION 65. THIS
PRODUCT DOES NOT CONTAIN ANY CHEMICALS RECOGNIZED BY THE STATE OF
CALIFORNIA TO CAUSE CANCER AND/OR BIRTH DEFECTS OR REPRODUCTIVE
HARM.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.